Mechanistic studies of a reaction promoted by the [YLi3[tris(binaphthoxide)]] complex: are three 1,1'-bi-2-naphthol units in a rare-earth-alkali-metal heterobimetallic complex necessary?
نویسندگان
چکیده
منابع مشابه
Catalytic asymmetric nitro-Mannich reactions with a Yb/K heterobimetallic catalyst.
A catalytic asymmetric nitro-Mannich (aza-Henry) reaction with rare earth metal/alkali metal heterobimetallic catalysts is described. A Yb/K heterobimetallic catalyst assembled by an amide-based ligand promoted the asymmetric nitro-Mannich reaction to afford enantioenriched anti-b-nitroamines in up to 86% ee. Facile reduction of the nitro functionality allowed for efficient access to optically ...
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ورودعنوان ژورنال:
- Angewandte Chemie
دوره 43 34 شماره
صفحات -
تاریخ انتشار 2004